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Susannah Scott, April 10

Susannah Scott

Susannah Scott

Distinguished Professor of Chemical Engineering and Chemistry & Biochemistry
University of California, Santa Barbara

Valorization of polyolefins via catalytic upcycling, from monomers to higher value molecules

April 10

4:00–5:00 p.m.
Physics/Astronomy Auditorium A118

Abstract

The use of polyolefins to make small molecules, not limited to monomers which can be repolymerized, is an intriguing approach to recycle carbon and thereby keep plastic out of the natural environment. While catalytic hydrogenolysis leads to lower value alkanes, hydrogen redistribution in the absence of added H2 can achieve tandem hydrogenolysis and dehydrocycloaromatization, resulting in higher value aromatics at moderate reaction temperatures.

The coupled reactions are greatly accelerated by the use of bifunctional hydrocracking catalysts whose acidity can be used to tune the selectivity towards surfactant-range alkylaromatics. The key rate-determining and selectivity-controlling steps are shown to involve Brønsted acid catalysis. Several other tandem processes, including the selective conversion of polyethylene to monomers under mild reaction conditions, can be designed to achieve alternative desired reaction outcomes.

Bio

Susannah Scott is a Distinguished Professor in both Chemical Engineering and in Chemistry & Biochemistry at the University of California, Santa Barbara. She received her Ph.D. in Inorganic Chemistry from Iowa State University, under the direction of Jim Espenson and Andreja Bakac, for her work on the activation of O2 and transition metal-catalyzed oxidation mechanisms. She was awarded a NATO Postdoctoral Fellowship for work with Jean-Marie Basset at the Institut de recherches sur la catalyse (CNRS) in Lyon, France. In 1994, she joined the faculty of the University of Ottawa (Canada), where she was named a Canada Research Chair. In 2003, she moved to the University of California, Santa Barbara, where she currently holds the Duncan and Suzanne Mellichamp Chair in Sustainable Catalysis and is Chair of the Santa Barbara Division of the University of California’s Academic Senate. She is an Executive Editor for ACS Catalysis, and a member of the Board of Reviewing Editors for Science.

Susannah's research interests include the design of heterogeneous catalysts with well-defined active sites for the conversion of conventional and unconventional carbon-based feedstocks, as well as environmental catalysts to promote air and water quality. She develops new kinetic and spectroscopic methods to probe reaction mechanisms at interfaces.

In 2014, she founded the Mellichamp Academic Initiative in Sustainable Manufacturing and Product Design at UC Santa Barbara, where she leads an interdisciplinary program in sustainability research and education.